Spring 2023 - CHEM 832 G100
Organometallic Chemistry (3)
Class Number: 6947
Delivery Method: In Person
Overview
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Course Times + Location:
Jan 4 – Apr 11, 2023: Wed, 2:30–4:20 p.m.
BurnabyJan 4 – Apr 11, 2023: Fri, 2:30–4:20 p.m.
Burnaby -
Exam Times + Location:
Apr 22, 2023
Sat, 8:30–11:30 a.m.
Burnaby
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Instructor:
Daniel Leznoff
dleznoff@sfu.ca
1 778 782-4406
Description
CALENDAR DESCRIPTION:
An advanced treatment of the synthesis, structures, reactions and spectroscopic identification of inorganic compounds.
COURSE DETAILS:
Please note, this course outline was accurate at the time of publication but is subject to change.
Mode of Teaching:
3 lecture hours/week; 1 tutorial hour/week
Lecture: Synchronous
Tutorial: Synchronous
Course Description:
This course provides an introduction to organometallic chemistry by surveying the common classes of carbon-based ligands, their characterization and reactivity. Application of organometallics in catalysis, organic synthesis and biology will be examined.
General Course Outline Overview and Introduction to Organometallic Chemistry
- Basic principles, bonding concepts, characterization tools and ancillary ligands.
Synthesis, Characterization and Bonding Survey of Organometallic Ligands
- The 18-electron rule, Metal-carbonyls and related ligands Main group and Transition-Metal-hydrides and σ-alkyls Metal-carbon π-bonded and multiple-bonded ligands.
- Common reaction mechanisms and elementary steps Organometallic catalysis for small molecule formation: Asymmetric hydrogenation, hydroformylation, acetic acid synthesis Catalytic olefin polymerization, oligomerization and metathesis Reactivity of metal-bound ligands.
- Activation of small, inert molecules (N2, CO2, CH4, fluorocarbons) Reactivity of Metal-Metal bonded systems Paramagnetic Organometallic complexes Bio-organometallic systems.
Grading
- Midterm Exam 25%
- Make a Problem Set 25%
- Presentation 25%
- Final Exam 25%
NOTES:
Online Exam Invigilation: Students completing exams remotely must comply with the online invigilation procedures implemented by the course instructor.
Materials
MATERIALS + SUPPLIES:
Technology Requirements: Students are required to have a desktop or laptop computer, high-speed internet access, and a webcam and microphone (built-in or external) to participate in online courses.
RECOMMENDED READING:
Robert H .Crabtree, The Organometallic Chemistry of the Transition Metals, 6th edition, 2014, Publisher: Wiley.
A.F.Hill, Organotransition Metal Chemistry, 2002, RSC Basic Concepts in Chemistry Series.
Or any other organometallic chemistry text.
REQUIRED READING NOTES:
Your personalized Course Material list, including digital and physical textbooks, are available through the SFU Bookstore website by simply entering your Computing ID at: shop.sfu.ca/course-materials/my-personalized-course-materials.
Graduate Studies Notes:
Important dates and deadlines for graduate students are found here: http://www.sfu.ca/dean-gradstudies/current/important_dates/guidelines.html. The deadline to drop a course with a 100% refund is the end of week 2. The deadline to drop with no notation on your transcript is the end of week 3.
Registrar Notes:
ACADEMIC INTEGRITY: YOUR WORK, YOUR SUCCESS
SFU’s Academic Integrity website http://www.sfu.ca/students/academicintegrity.html is filled with information on what is meant by academic dishonesty, where you can find resources to help with your studies and the consequences of cheating. Check out the site for more information and videos that help explain the issues in plain English.
Each student is responsible for his or her conduct as it affects the university community. Academic dishonesty, in whatever form, is ultimately destructive of the values of the university. Furthermore, it is unfair and discouraging to the majority of students who pursue their studies honestly. Scholarly integrity is required of all members of the university. http://www.sfu.ca/policies/gazette/student/s10-01.html